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The hydrolysis of phenylhydroxamic acid in concentrated aqueous sodium hydroxide

โœ Scribed by V.S. Bhuva; A.J. Buglass

Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
121 KB
Volume
25
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Phenylhydroxamic

acid undergoes hydrolysis in concentrated NaOH via a complex mechanism: a maximum is observed in the plot of k, versus [NaOH] which is attributed to the existence of one or more pre-equilibria influencing the rate-limiting step.

Hydroxamic acids are-known to undergo hydrolysis in acidic, neutral and alkaline media.lm4 The reactions in aqueous NaOH, hourever, have been studied mainly at either lour ionic strength or in l-3 conditions of constant ionic strength.

An outstanding feature of these studies.is the

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