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The Hydrolysis of Carboxylic Anhydrides. VII. 1,2 Electrolyte Effects on the Acid Hydrolysis

โœ Scribed by Bunton, C. A.; Fendler, J. H.


Book ID
126844995
Publisher
American Chemical Society
Year
1966
Tongue
English
Weight
1006 KB
Volume
31
Category
Article
ISSN
0022-3263

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The pyridine catalysed hydrolysis of car
โœ C.A. Bunton; N.A. Fuller; S.G. Perry; V.J. Shiner ๐Ÿ“‚ Article ๐Ÿ“… 1961 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 122 KB

TERTIARY amine:;, e.g. pyridine, are effective catalysts of the hydrolysis of carboxylic anhydrides. Pyridine is believed to act by converting the anhydride into an acylpyridinium ion (I). Both the formation of this ion, step 1, and its breakdown to products, step 3, have at times been postulated as