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Transition state structures for the hydrolysis of cyclic and acyclic carboxylic acid anhydrides

โœ Scribed by Davis, Kenneth R.; Hogg, John L.

Book ID
126946286
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
882 KB
Volume
48
Category
Article
ISSN
0022-3263

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Transition state structure for the intra
Transition state structure for the intramolecular catalysis by carboxylate of phenyl hydrogen malonate hydrolysis
โœ K.S. Venkatasubban; John L. Hogg ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 193 KB

The intmmoZecuZm cataZysis by carboxyZ&e of pheny2 hydrogen ndonate hydrolysis has been showa to involve a sin@!e water moledle in a d-membered ring transition state. The question of the structural requirements for intramolecular proton transfers has received considerable attention. Gandour has pre