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The Hydrogenation of Olefines. III. The Disproportionation to Combination Ratios of the Interaction of Alkyl Radicals

โœ Scribed by Boddy, P. J.; Robb, J. C.

Book ID
120145017
Publisher
The Royal Society
Year
1959
Tongue
English
Weight
601 KB
Volume
249
Category
Article
ISSN
0962-8444

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๐Ÿ“œ SIMILAR VOLUMES

Disproportionation-combination ratios of
Disproportionation-combination ratios of small alkyl radicals formed by the mercury-photosensitized hydrogenation of olefins in the gas phase
โœ W. E. Falconer; W. A. Sunder ๐Ÿ“‚ Article ๐Ÿ“… 1971 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 659 KB

Disproportionation-combination ratios have been obtained for small alkyl radicals produced in the mercury-photosensitized hydrogenation of ethylene, propylene, butene-1, butene-2, and isobutene. For conditions favoring thermalized radicals, kd/k, (ethyl, ethyl) = 0.14, kd/k, (isopropyl, isopropyl) =

The disproportionation and combination o
The disproportionation and combination of alkyl radicals
โœ R. S. Konar ๐Ÿ“‚ Article ๐Ÿ“… 1970 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 159 KB

Several attempts have been made to correlate the disproportionation and the combination rate constant ratio, k,/k,, of the alkyl radicals with the entropy change of the processes [ 1-31. Bradley [I] made a specific suggestion that the k,/k, ratio is a function of the entropy change of the processes