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The hydrogen peroxide–iodic acid–manganese (ii)–acetone oscillating system: Further observations

✍ Scribed by David O. Cooke

Book ID
102929890
Publisher
John Wiley and Sons
Year
1980
Tongue
English
Weight
662 KB
Volume
12
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

The redox potential and iodine concentration behavior of the title reaction and component reactions have been examined. The effect of hydrogen peroxide, potassium iodate, manganese (II) sulfate, sulfuric acid, and acetone concentration on the time period and redox potential behavior is reported. Iodine production and consumption rates for the component reactions are given, and some mechanistic suggestions, involving iodine dioxide as the one electron oxidant, are made.

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Oxidations by the system “hydrogen peroxide - manganese(IV) complex - acetic acid” — Part II. Hydroperoxidation and hydroxylation of alkanes in acetonitrile
✍ Georgiy B Shul'pin; Georg Süss-Fink; John R Lindsay Smith 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 694 KB

Higher alkanes (cyclohexane, n-pentane, n-heptane, methylbutane, 2-and 3methylpentanes, 3-methylhexane, cis-and trans-deealins) are oxidized at 20 °C by H202 in air in acetonitrile (or nitromethane) solution in the presence of the manganese(IV) salt [L2Mn203](PF6)2 (L = 1,4,7-trimethyl-1,4-7-triazac