Observations on the hydrogen peroxide-iodic acid-manganese(II)-organic species oscillating system
✍ Scribed by Cooke, D. O.
- Book ID
- 112682946
- Publisher
- Springer
- Year
- 1976
- Tongue
- English
- Weight
- 15 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0133-1736
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## Abstract The redox potential and iodine concentration behavior of the title reaction and component reactions have been examined. The effect of hydrogen peroxide, potassium iodate, manganese (II) sulfate, sulfuric acid, and acetone concentration on the time period and redox potential behavior is
The iodine concentration behaviour of the title reaction has been investigated. Production and consumption rates under various conditions are reported. Some mechanistic details are suggested.
Higher alkanes (cyclohexane, n-pentane, n-heptane, methylbutane, 2-and 3methylpentanes, 3-methylhexane, cis-and trans-deealins) are oxidized at 20 °C by H202 in air in acetonitrile (or nitromethane) solution in the presence of the manganese(IV) salt [L2Mn203](PF6)2 (L = 1,4,7-trimethyl-1,4-7-triazac