The Homogeneous Decomposition of Ethyl Chlorocarbonate
โ Scribed by Choppin, A. R.; Frediani, H. A.; Kirby, G. F.
- Book ID
- 126062065
- Publisher
- American Chemical Society
- Year
- 1939
- Tongue
- English
- Weight
- 485 KB
- Volume
- 61
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
## Abstract A convenient method for the preparation of ethyl chlorocarbonateโ^14^C is described. This has led to a facile synthesis of Nโmethylโ^14^C secondary amines by lithium aluminum hydride reduction of an intermediate ^14^Cโcarbamate. The reaction has also been employed in the preparation of
## Abstract Benzoguanamine (2,4โdiaminoโ6โphenylโsโtriazine) and acetoguanamine (2,4โdiaminoโ6โmethylโsโtriazine) both react with an excess of ethyl chlorocarbonate; in this reaction two hydrogen atoms from the guanamines are replaced by two carbethoxy groups. The I.R. spectrum reveals that this do