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The higher rydberg states of formaldehyde

✍ Scribed by C.R. Drury-Lessard; D.C. Moule

Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
838 KB
Volume
47
Category
Article
ISSN
0009-2614

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✦ Synopsis

Tire assignment of tbc vacuum uitrevioiet transitions in formaldehyde below

1500 A is reexamined. Rydbeg series involvin: transitions from the nonbonding n orbital to s, p,,, pr, d and f orbinds are assigned in the spectrum_ The fust ioniaation potentials in HlCO and DsCO are reevaluated from the spectra1 data to be 10.874 f 0.002 eV end IO.901 -+ 0.006 eV respectively.

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The absorption spectrum of \(\mathrm{S}_{2}\) has been observed down to \(400 \AA\) on the SA63 line of SUPERACO (LURE) in Orsay, France. Two already reported Rydberg series converging to the \(X^{2} \Pi_{g}\) ground state of \(\mathrm{S}_{2}^{+}, \pi_{u}^{4} \pi_{g}^{2} X^{3} \Sigma_{g}^{-} \righta