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The high temperature pyrolysis of ethylbenzene

โœ Scribed by K. M. Pamidimukkala; R. D. Kern

Publisher
John Wiley and Sons
Year
1986
Tongue
English
Weight
556 KB
Volume
18
Category
Article
ISSN
0538-8066

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โœฆ Synopsis

The thermal decomposition of ethylbenzene has been investigated behind reflected shock waves over the temperature and pressure ranges of 1350-2080 K and 0.25-0.5 atm using a 1.6% CxH,o-Ne mixture. Major products of the pyrolysis are C7H,, C,Hi, CGHG, C4H2, C,H,, C2H2, and CH,; CRH, appears throughout the temperature range as a minor product. Comparison of the product profiles obtained by time-of-flight mass spectrometry and the results of model calculations strongly supports the initiation step of p C-C bond homolysis for C,H,o dissociation. A 51 kinetic step reaction mechanism with 24 species was formulated to model the temperature and time dependence of the major products observed in our experiments.

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