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High-temperature pyrolysis of dimethyl ether

โœ Scribed by D. Aronowitz; D. Naegeli

Publisher
John Wiley and Sons
Year
1977
Tongue
English
Weight
390 KB
Volume
9
Category
Article
ISSN
0538-8066

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โœฆ Synopsis

The kinetics of pyrolysis of dimethyl ether were studied in an adiabatic flow reactor at temperatures between 790 and 950ยฐC. The unimolecular rate constant for the initiating step CH30CH3 = CH30 + CH, was found to be k, = 2.16 X 1015e-76.@""RTse~-1. Aspects of the kinetic mechanism are discussed and a system postulated to account for the high-temperature products.

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