Vibration-rotation spectra of the parallel \(v_{5}\) band of hexafluorodisilane have been measured in a supersonic free jet with \(0.001 \mathrm{~cm}^{-1}\) resolution. Three isotopic species, \({ }^{28,28} \mathrm{Si}_{2} \mathrm{~F}_{6},{ }^{28,29} \mathrm{Si}_{2} \mathrm{~F}_{6}\), and \({ }^{28.
The High-Resolution ν7 Perpendicular Band of Jet-Cooled Si2F6
✍ Scribed by V. Tosa; R.D. Urban; M. Takami; K. Takeuchi
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 506 KB
- Volume
- 172
- Category
- Article
- ISSN
- 0022-2852
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✦ Synopsis
The vibration-rotation spectrum of the perpendicular band (\nu_{7}) of ({ }^{28,28} \mathrm{Si}{2} \mathrm{~F}{6}) has been studied in a supersonic free jet with (0.001 \mathrm{~cm}^{-1}) resolution. The spectrum covering the (K \Delta K=-17) to 8 subbands shows a local perturbation for (K \Delta K>2). The whole spectrum has been successfully analyzed by assuming a Fermi interaction from a very close combination state. Also, the (Q) branch of the (\nu_{7}) band of ({ }^{28.29} \mathrm{Si}{2} \mathrm{~F}{6}) has been identified. (c 1995 Academic Press, Inc.
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