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The Hg 6(3P1) photosensitized decomposition of 1,1,2,2-tetrafluorocyclobutane

✍ Scribed by A.R. Ravishankara; Robert J. Hanrahan

Publisher: Elsevier Science
Year: 1977
Weight: 994 KB
Volume: 7
Category: Article
ISSN: 0047-2670
DOI: 10.1016/0047-2670(77)87013-5

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The quantum yields of the c&+tm,ls and fnms+cis Hg 6(3P1) photosensitized isomerizations of butene-2 are both 0.50 + 0.02 for butene2pressures > 30 torr. The formation of excited mercury-butene-2 complexes, invoked by Tsunashima and Sato to explain an apparent loss of incident photons, does not occu