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The Heats of Ionization of Water, Ammonium Hydroxide, Carbonic, Phosphoric, and Sulfuric Acids. The Variation of Ionization Constants with Temperature and the Entropy Change with Ionization

โœ Scribed by Pitzer, Kenneth S.

Book ID
124048416
Publisher
American Chemical Society
Year
1937
Tongue
English
Weight
673 KB
Volume
59
Category
Article
ISSN
0002-7863

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Enthalpy and entropy changes associated with the ionization of hydroxyethylenediaminetriacetic acid
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Enthalpy ck anges associated with the three ionizations of hydroxyethylenediarninetriacetic acid have been measured calorimetrically. The values reported for 25ยฐC and p = 0.1 (KCI) are AH1 = -1.12&0.12, AH2 = +3.09&0.05 and AH3 = +6.65 h0.08 kcal.mole-l, respectively. From these data and from the ac