The heat of formation of C3H2+
โ Scribed by D. Smith; N.G. Adams; E.E. Ferguson
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 318 KB
- Volume
- 61
- Category
- Article
- ISSN
- 0168-1176
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The initial rates of formation of the major products in the thermal reactions of ethylene at temperatures in the neighborhood of 800 K have been measured in the presence and absence of the additives neopentane and ethane. It has been shown that in the absence of the additive the main initiation proc
concluded [301 that CFH, + CF,H + CFH + CF,H, did not occur. Taking LUP > 0 gives a similar result, AH;
Ab initio molecular calculations carried out at the UQCISD (T ) /6-3 1 1 + + G ( 3df, 2p) and RCCSD (T ) /cc-pVTZ levels have been used to re-examine the heats of formation of the [C, Hs, N] +' radical cations and related species. The following values have been obtained: AH&s8 (H&NH) +' = 1046+ 10 k