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Orbital energy and entropy correlations for disproportionation versus combination in the reactions of CFyH(3−y) radicals (y = 0,1,2,3) with C2H5 radicals. The heat of formation of CHF

✍ Scribed by G. O. Pritchard; W. B. Nilsson; B. Kirtman

Publisher: John Wiley and Sons
Year: 1984
Tongue: English
Weight: 317 KB
Volume: 16
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550161216

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✦ Synopsis

concluded [301 that CFH, + CF,H + CFH + CF,H, did not occur.

Taking LUP > 0 gives a similar result, AH;

📜 SIMILAR VOLUMES

Disproportionation reactions between alk

Disproportionation reactions between alkyl and fluoroalkyl radicals. III. A reassessment of Δ values for CFyH(3−y) radicals (y = 1,2,3) with C2H5 radicals

✍ G. O. Pritchard; K. A. Johnson; W. B. Nilsson 📂 Article 📅 1985 🏛 John Wiley and Sons 🌐 English ⚖ 391 KB

New determinations of the disproportionation and combination ratios between CFZH and CzH5 radicals yield (the hydrogen acceptor radical is given first) A(CF2H, CzH5) = 0.068 t\_ 0.008, and A(C2H5,CF2H) = 0.37 t\_ 0.01. A reevaluation of the existing data on CFHP and CF3 radicals leads t o t h e foll