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The ground state properties of 1,2,3,4-tetrachloro-5,6-diphenylcalicene

✍ Scribed by Ichiro Murata; Masako Ueno; Yoshio Kitahara; Haruyuki Watanabe

Publisher
Elsevier Science
Year
1966
Tongue
French
Weight
246 KB
Volume
7
Category
Article
ISSN
0040-4039

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✦ Synopsis

In the previous paper (1) we have reported the synthesis and some properties of 1,2,3,4-tetraohloro-fi,bdlphenyloalloene (I).

Theoretloal oonslderatlons (2) have predloted that the oalloene system (II) would have a stable.olosed-shell eleotronlo oonflguratlon and that the dlpolar resonanoe struoture (IIa) would make au unusually large oontrlbutlon to Its ground state due to a oharge transfer from the eleotron-donatlng threemembered ring towards the eleotron-aooeptlng five-membered ring.

Very reoently, however, Dewar and Gleloher (3) have reported the oaloulatlons for oalloene and Its beneo derivatives by the semll To whom oommunloatlons should be addressed.

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