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The glass, the glassy state and the Alice number

✍ Scribed by Ivailo B. Gugov


Book ID
107859597
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
466 KB
Volume
280-281
Category
Article
ISSN
0040-6031

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πŸ“œ SIMILAR VOLUMES


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✍ Rehage, GΓΌnther ;Frenzel, JΓΌrgen πŸ“‚ Article πŸ“… 1982 πŸ› Wiley (John Wiley & Sons) 🌐 English βš– 664 KB

## Abstract PVT‐measurements on atactic polystyrene shows that the Ehrenfest equations, which describe a thermodynamic transformation of the second order, are not applicable for the glass transition. The introduction of one internal ordering parameter ΞΆ in addition to the conventional variables T a

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According to Ehrenfest classification, the glass transition is a second-order phase transition. Controversy, however, remains due to the discrepancy between experiment and the Ehrenfest relations and thereby their prediction of unity of the Prigogine-Defay ratio in particular. In this article, we co