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Statistical thermodynamics of the liquid state, the liquid-glass transition and the glassy state of polymers

✍ Scribed by R. Simha

Publisher
Springer-Verlag
Year
1975
Tongue
English
Weight
713 KB
Volume
14
Category
Article
ISSN
0035-4511

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According to Ehrenfest classification, the glass transition is a second-order phase transition. Controversy, however, remains due to the discrepancy between experiment and the Ehrenfest relations and thereby their prediction of unity of the Prigogine-Defay ratio in particular. In this article, we co