The Gibbs principle for the equilibrium of systems with two simple or composed phases
โ Scribed by Donatella Iannece; Antonio Romano; Giulio Starita
- Publisher
- Springer Netherlands
- Year
- 1990
- Tongue
- English
- Weight
- 644 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0025-6455
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Rules are given which should assist in the use of the equation dy y(l-Y) IdP \_=---[ 1 dx (y-x) Pdx for predicting vapour compositions from total pressure data. A discussion is also given of the values of dy dx at the terminal points of the composition range and at the azeotropic point.
A method is presented which allows the calculation of phase diagrams (spinodal, binodal and tie lines) on the basis of the Gibbs energy of mixing AG. No derivatives of AG with respect to the composition variables are required. This method is particularly useful in cases where the composition depende
The vapour-hqmd eqmhbrla of the system acetlc acid-toluene have been modelled both by extstmg methods and by a new model mcorporatmg a concentration dependent hquld phase association constant The vahdtty of the models was tested by carrying out Barker fits on the Isothermal data avadable m the liter