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The geometry of vibration-induced rotational mixing in molecules

โœ Scribed by D.K. Sahm; T. Uzer

Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
510 KB
Volume
163
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

In highly vibrationally excited molecules, rotational mixing describes the breakdown of K, the projection of the total molecular angular momentum on a body-fixed axis, as a good quantum number. We present a geometrical construction which illustrates the role of molecular vibrations in bringing about this breakdown.

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