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The generation of sharp fluctuations in the linewidths of electronic absorption spectra. Application to benzene

✍ Scribed by Gad Fischer; Ron Naaman

Publisher: Elsevier Science
Year: 1976
Tongue: English
Weight: 441 KB
Volume: 42
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(76)80682-3

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✦ Synopsis

A three state model is proposed for the explanation of sharp and large fluctuations of linewidths in electronic absorption spectra. The "channel 3" enigma of benzene is explained and on the basis of the ener,T dependence of the linebroadening in the tBZu state, vibrational structure is determined of a near-lying triplet state.

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## Abstract The validity of a superimposability principle for the electronic spectra of disubstituted benzene derivatives, proposed by __Doub__ and __Vandenbelt__^5^ to interpret the principal absorption bands of some trisubstituted benzene derivatives is discussed for __p__‐aminosalicylic acid, β‐