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The Generation of a Metallocene-Fused Imidazol-2-ylidene and Its Mercury Complex

โœ Scribed by Anthony J. Arduengo III; Daniela Tapu; William J. Marshall


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
325 KB
Volume
117
Category
Article
ISSN
0044-8249

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## The reaction of I,3-dimethylimidazolium chloride with Hg(O,CCH,), afforded a bis(carbene)mercuty (II) complex (2), which is characterized by multinuclear N M R spectroscopy (IH, 13C, 15N, and 199Hg) and by single-crystal X-ray analysis. As a consequence of chloride-ion interaction with the mercur