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Reaction of the N-heterocyclic carbene, 1,3-dimesityl- imidazol-2-ylidene, with a uranyl triflate complex, UO2(OTf)2(thf)3

โœ Scribed by Susan M. Oldham; Brian L. Scott; Warren J. Oldham Jr


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
129 KB
Volume
20
Category
Article
ISSN
0268-2605

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Reversible CH Bond Activation Reactions
โœ Markโ€…J. Chilvers; Rodolpheโ€…F.โ€…R. Jazzar; Maryโ€…F. Mahon; Michaelโ€…K. Whittlesey ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 118 KB ๐Ÿ‘ 2 views

## Abstract Thermolysis of Ru(IMes)(dppp)(CO)H~2~ (1, IMes=1,3โ€dimesitylโ€1,3โ€dihydroโ€2__H__โ€imidazolโ€2โ€ylidene; dppp=Ph~2~PCH~2~CH~2~CH~2~PPh~2~) in the presence of trimethylvinylsilane yields Ru(IMes')(dppp)(CO)H (2) resulting from intramolecular ArCH~2~โ€“H C๏ฃฟH bond activation of the __N__โ€heterocy