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The gauche interaction in trans-1,2-dimethylcyclohexane

✍ Scribed by Muthiah Manoharan; Ernest L. Eliel

Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
200 KB
Volume
24
Category
Article
ISSN
0040-4039

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✦ Synopsis

The gauche interaction in the diequatorial conformation of trans-1,2-dimethylcyclohexane is found to be 0.74CO.09 kcal/mol (3.10+0.38 kJ/mol).

πŸ“œ SIMILAR VOLUMES

Trapping of unstable molecular conformat
Trapping of unstable molecular conformations in argon matrices: Gauche- and trans-1,2-difluoroethane
✍ P. Huber-WΓ€lchli; Hs.H. GΓΌnthard πŸ“‚ Article πŸ“… 1975 πŸ› Elsevier Science 🌐 English βš– 510 KB

Experiments are reported which describe the trapping of the unstable fruns conformer of 1.2difluoroethane in argon matrices. Assignments of the infrared spectra of the guuche and rrans conformers are given. The latter is shown to have a 600 c-al/ma1 higher free enthalpy. 1,2difluoroethane (DFE) may