## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
The gauche effect : On the nature of the interaction between electronegative substituents in trans-1,2-disubstituted cyclohexanes
β Scribed by Nikolai S. Zefirov; V.V. Samoshin; O.A. Subbotin; V.I. Baranenkov; Saul Wolfe
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- French
- Weight
- 567 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0040-4020
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## Abstract ^13^C NMR spectra of six epimeric substituted 4βhydroxypiperidines and two corresponding piperidines were recorded. Substituent parameters for equatorial methyl, __gem__βdimethyl, equatorial hydroxy and axial hydroxy groups were calculated from the ^13^C chemical shifts of these compoun
The solvolysis rates of 1-aryl-1-(p-methoxyphenyl)-2,2,2-trifluoroethyl and 1-aryl-1-(p-phenoxyphenyl)-2,2,2-trifluoroethyl bromides and chlorides were conductimetrically measured at 25.0 Β°C in 80% aqueous ethanol. The solvolysis rates of 1-(p-methylphenyl)-fixed series were also set up to analyze t