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The gas-phase dissociation of a new polyazapolycylic nitramine: Hexanitrohexazaisowurtzitane

✍ Scribed by Robert J. Doyle Jr

Publisher: John Wiley and Sons
Year: 1991
Tongue: English
Weight: 313 KB
Volume: 26
Category: Article
ISSN: 1076-5174
DOI: 10.1002/oms.1210260812

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✦ Synopsis

A recent report described the synthesis of a new polyazapolycyclic ring system, 2,4,6,8,10,12-hexabenzyl-2,4,6,8,10,12hexaazatetracyclo[5.5.0.05*9.03~'1]dodecane (hexabenzylhexaazaisowurtzitane, HBIW)' by the condensation of benzylamine with glyoxal. Condensation reactions of phenylsubstituted benzylamines with glyoxal were shown to yield six phenyl-substituted HBIW derivatives. The authors of the aforementioned report have recently achieved the synthesis of a similar polyazapolycyclic ring system with the six benzyl groups of HBIW replaced by six nitro groups, 2,4,6,8,10,12-

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