Generation of the Phenyl Cation by Dissociative Ionization of a Dienynyl Bromide in the Gas Phase

✍ Scribed by Gisbert Depke; Prof. Dr. Michael Hanack; Wolfgang Hümmer; Prof. Dr. Helmut Schwarz

• Publisher: John Wiley and Sons
• Year: 1983
• Tongue: English
• Weight: 235 KB
• Volume: 22
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/anie.198307861

✦ Synopsis

The monocondensation product 2, which, in the case of the tert-butyl derivative could be detected 3'P-NMR-spectroscopically in the reaction solution at -90°C'21, cannot be observed during the synthesis of 3, apparently because of the drastic reaction conditions[51.