The gas-phase and solution-phase free energy surfaces for carbon dioxide reaction with hydroxide (CO2 + OH- .fwdarw. HCO3-)
β Scribed by Peng, Z.; Merz, Kenneth M.
- Book ID
- 127333130
- Publisher
- American Chemical Society
- Year
- 1992
- Tongue
- English
- Weight
- 318 KB
- Volume
- 114
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
The complex W (CO) 5 ( C02) has been observed in the gas phase by time-resolved infrared spectroscopy following 355 nm laser photolysis of W (CO)6 in the presence of CO,. The complex was shown to be in equilibrium with its precursor W (CO) s at room temperature and the bond energy for binding of CO2
Recently, Atkinson et al. [l] reported measurements on the reaction of ozone with a series of carbonyls. In that study a correlation between ozone addition and hydroxyl-radical addition reactions was employed to predict OH addition coefficients for acrolein and crotonaldehyde of approximately 2 X an