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The freeon theory of molecular magnets. III. The linear polyene model

✍ Scribed by F. A. Matsen

Publisher: John Wiley and Sons
Year: 1999
Tongue: English
Weight: 171 KB
Volume: 72
Category: Article
ISSN: 0020-7608
DOI: 10.1002/(sici)1097-461x(1999)72:4<325::aid-qua15>3.0.co;2-4

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✦ Synopsis

We applied freeon dynamics to the computation of the magnetic coupling constant of the linear polyene model of the AXA molecular magnet. Our spectrum is the superposition of the freeon exchange and the linearized Huckel᎐Hubbard spectra. The computed magnetic coupling constant goes from FM to AFM coupling as a linear function of the ratio of the hopping integral to the zero-order ferromagnetic coupling constant.

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