We applied freeon dynamics to the computation of the magnetic coupling constant of the linear polyene model of the AXA molecular magnet. Our spectrum is the superposition of the freeon exchange and the linearized HuckelαHubbard spectra. The computed magnetic coupling constant goes from FM to AFM cou
The freeon theory of magnetism. II. Molecular magnets
β Scribed by F. A. Matsen; L. L. Campbell
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 159 KB
- Volume
- 65
- Category
- Article
- ISSN
- 0020-7608
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β¦ Synopsis
In Article I, we showed that the freeon-exchange theory of magnetic coupling is a viable alternative to the widely used spin-exchange theory. In Article II, we are concerned with the symmetric-bridge, molecular magnet, AXB, where A and B are magnetic atoms and X is the bridge. The symmetric-bridge molecular magnet is of particular interest because the major features of its spectrum and its coupling constants are obtained by means of the two-electron, two-site freeon theory. We exhibit one example of ferromagnetic coupling, J ) 0 and one of antiferromagnetic coupling, J -0.
π SIMILAR VOLUMES
The freeon theory of magnetism is a viable alternative to the well-known Heisenberg theory. In particular, the freeon-exchange theory provides a deeper insight into the nature of the magnetic interaction than does the spin-exchange theory. In addition, it avoids the superfluous M quantum number in z
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