comparisons of the trideutero-glycine EPK spectrum with the EPR spectr a of non-deuterated glycine are open to question.
The free radicals in irradiated glycines. A comment
β Scribed by M.J.A. de Bie; R. Braams
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- English
- Weight
- 221 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
In X-and Y-irAdiated polycrystalline glycines the.radiolytic behaviour is dependent on the crystal structure and/or the extent of deuterium Iabelling. This is due to a selective transformation of the formed 'CH-COO' radical into the H$'-'CH-COO-radical and not to a selective decay of the 'CH2 -COO' radical.
π SIMILAR VOLUMES
Comments are given on a recent interpretation 01 the EPR spectra of irradiated solid glycine. ft ES emphasised that IVIorton's assumption.for deuterated giycines still seems necessary. Explanation is given for the changes of spectra after irradiation.
The ESR spectrum of In electron irradiated sample of highly puriticd adnmantanc is prcsentcd. Arguments are presented for the assignment of the radical as I-adamantyl.