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Free radicals trapped in polyethylene matrix: 1. Location of the alkyl radicals in irradiated polyethylene

✍ Scribed by Shigetaka Shimada; Masatoshi Maeda; Yasurō Hori; Hisatsugu Kashiwabara


Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
480 KB
Volume
18
Category
Article
ISSN
0032-3861

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Influence of pressure of free radical de
✍ F. Szöcs; O. Rostašova; J. Tiňo; J. Plaček 📂 Article 📅 1974 🏛 Elsevier Science 🌐 English ⚖ 166 KB

Information is given on the effect of high pressure on the decay of free radicals in irradiated polyethylene. The dependence of the rate constant for decay on pressure (1-13,000 atm) was determined at 80, 90, 100 and 110 °. The mechanism of the effect of pressure on the rate constant and activation