✦ LIBER ✦

The fragmentation of C2H6N+ ions: an alternative mechanism

✍ Scribed by Vincenzo Barone; Francesco Lelj; Pasquale Grande; Nino Russo; Marirosa Toscano

Publisher: Elsevier Science
Year: 1987
Tongue: English
Weight: 360 KB
Volume: 133
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(87)80076-3

No coin nor oath required. For personal study only.

✦ Synopsis

An MNDO characterisation of the potential energy surface of the C2HsN+ system provides a coherent picture which can explain all the experimental observations. The distinctive feature of this study is the elucidation of the role played by several intermediates in the loss of acetylene and molecular hydrogen from the most stable ions [ CHSCHNH2 ] + and [ CH3NHCH2] + . Ab initio computations for the most significant energy extrema confirm the MNDO results.

📜 SIMILAR VOLUMES

The isomerization mechanism of alkylamin

The isomerization mechanism of alkylamines: Structure of [C2H6N]+ and [C3H8N]+ fragment ions

✍ H. E. Audier; A. Milliet; G. Sozzi; J. P. Denhez 📂 Article 📅 1984 🏛 John Wiley and Sons 🌐 English ⚖ 185 KB

On the mechanisms of C6H6 ionization and

On the mechanisms of C6H6 ionization and fragmentation

✍ H.M. Rosenstock; K.E. McCulloh; F.P. Lossing 📂 Article 📅 1977 🏛 Elsevier Science ⚖ 959 KB

Energy dependence of the fragmentation o

Energy dependence of the fragmentation of some isomeric [C6H12]+˙ ions

✍ Jan A. Herman; Yip-Hoi Li; Alex. G. Harrison 📂 Article 📅 1982 🏛 John Wiley and Sons 🌐 English ⚖ 820 KB

Chemiluminescent ion-molecule rections o

Chemiluminescent ion-molecule rections of N+ ions with H2, CH4, C2H4, C2H6, C3H8

✍ I. Kusunoki; Ch. Ottinger; J. Simonis 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 463 KB

Low-energy fragmentations of five isomer

Low-energy fragmentations of five isomeric [H3, C, N, O2] +· ions

✍ M. Sirois; J. L. Holmes; C. E. C. A. Hop 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 English ⚖ 614 KB

The low-energy fragmentation characteristics of the [H, ,C,N,O,]+' isomers [H,CNOJ+' (a), [H,C=N(O)OHJ+' (b), [H,CONO]+' (c), [HC(O)NHOH]+' (d) and [HC(OH)=NOH]+' (e) were studied in detail by metastable ion mass spectrometry. In agreement with most earlier observations, appearance energy measuremen

Structure and fragmentation mechanism of

Structure and fragmentation mechanism of [C3H7S]+ ions

✍ W. J. Broer; W. D. Weringa 📂 Article 📅 1977 🏛 John Wiley and Sons 🌐 English ⚖ 344 KB