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The formyl CH--O hydrogen bond as a key to transition-state organization in enantioselective allylation, aldol and Diels-Alder reactions catalyzed by chiral lewis acids

✍ Scribed by E.J. Corey; David Barnes-Seeman; Thomas W. Lee

Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 276 KB
Volume: 38
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(97)00193-7

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The formyl CH--O hydrogen bond as a cri

The formyl CH--O hydrogen bond as a critical factor in enantioselective reactions of aldehydes, part 4. Aldol, ethylation, hydrocyanation and Diels-Alder reactions catalyzed by chiral B, Ti and Al lewis acids

✍ E.J. Corey; David Barnes-Seeman; Thomas W. Lee 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 287 KB

Formyl C-H--O hydrogen bonding provides a rational explanation of several diverse catalytic enantioselective addition reactions of aldehydes, as outlined in Figures 12345.