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The formyl CH--O hydrogen bond as a critical factor in enantioselective reactions of aldehydes, part 4. Aldol, ethylation, hydrocyanation and Diels-Alder reactions catalyzed by chiral B, Ti and Al lewis acids

✍ Scribed by E.J. Corey; David Barnes-Seeman; Thomas W. Lee

Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 287 KB
Volume: 38
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(97)00932-5

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✦ Synopsis

Formyl C-H--O hydrogen bonding provides a rational explanation of several diverse catalytic enantioselective addition reactions of aldehydes, as outlined in Figures 12345.

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