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The formation of unusual sultones during the rearrangement reactions of bicyclic ketones

✍ Scribed by David S. Brown; Harry Heaney; Steven V. Ley; Kenneth G. Mason; Pritpal Singh

Publisher
Elsevier Science
Year
1978
Tongue
French
Weight
195 KB
Volume
19
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES

Sultone formation in the sulphonation of
Sultone formation in the sulphonation of 9-tert-butylanthracene; an unusual rearrangement of the sultone involving the tert-butyl group.
✍ Freek van de Griendt; Hans Cerfontain πŸ“‚ Article πŸ“… 1978 πŸ› Elsevier Science 🌐 French βš– 191 KB

Recently we studied the aprotic sulphonation of a number of 9-alkylanthracenes which contained at least one o-hydrogen in the alkyl group. 2 We now report on 9-tert-butylanthracene (A) which behaves completely differently. Compound L was prepared by dehydration of 9-tert-butyl-9-hydroxy-9,10-dihy