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New Bicyclic Ketones and the Stereochemistry of Their Reaction with Carbanions

✍ Scribed by Dipl.-Chem. Petra Baierweck; Dipl.-Chem. Detlef Hoell; Prof. Dr. Klaus Müllen


Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
236 KB
Volume
24
Category
Article
ISSN
0044-8249

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The reactivity of the aziridinium cation towards the hydroxyl group of alcohols and phenols makes possible a simple synthesis of 2-alkoxyethylamines 111. If the reaction is carried out with a-hydroxy esters ( I ) and aziridinium tetrafluoroborate (2), one obtains first the salts (3) and then, by lo