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Reaction of the Carbanions of 2-(Alkylthio)thiolane 1-Oxides with Oxiranes

✍ Scribed by Barbara Schuler; Gunadi Adiwidjaja; Jürgen Voss


Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
295 KB
Volume
1999
Category
Article
ISSN
1434-193X

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✦ Synopsis


Thiolane 1-oxides


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✍ Andrzej Jończyk; Dariusz Lipiak; Paweł Stepniewski; Tadeusz Zdrojewski 📂 Article 📅 2010 🏛 Wiley (John Wiley & Sons) ⚖ 113 KB

In a search for a method of synthesis of a,/3 -unsaturated carbonyl compounds, we have turned our attention to the reactions of acyl anion equivalent^^-^, namely carbanions of 2-(dia1kylamino)aryla~etonitriles~ with acetylenes. It is well known that organometallic rea-gents5 as well as C-H acids, in