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The formation of the stable radicals ?CH2CN, CH3?CHCN and ?CH2CH2CN from the anions ?CH2CN, CH3?CHCN and ?CH2CH2CN in the gas phase. A joint experimental and theoretical study

✍ Scribed by Andreazza, Hayley J.; Fitzgerald, Mark; Bowie, John H.


Book ID
119950196
Publisher
Royal Society of Chemistry
Year
2006
Tongue
English
Weight
183 KB
Volume
4
Category
Article
ISSN
1477-0520

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Rate constants for the reactions of OH radicals and Cl atoms with CH,CH,NO>, CH,CH,CH,NO,, CH3CH2CH2CHzN02, and CH,CH2CH2CH,CH2N02 have been determined at 295+3 K and a total pressure of approximately 1 atm. The OH rate data were obtained using both the absolute rate technique of pulse radiolysis co