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THE FORMATION OF DI-PARA-TOLYL INCIDENTAL TO THE PREPARATION OF BENZYLMAGNESIUM CHLORIDE. THE PROBABLE PRELIMINARY FORMATION OF FREE RADICALS IN THE PREPARATION OF GRIGNARD REAGENTS

✍ Scribed by Gilman, Henry; Kirby, James E.


Book ID
127274729
Publisher
American Chemical Society
Year
1929
Tongue
English
Weight
427 KB
Volume
51
Category
Article
ISSN
0002-7863

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Concerning the formation of magnesium hy
✍ E.C. Ashby; T.L. Wiesemann; J.S. Bowers Jr.; J.T. Laemmle πŸ“‚ Article πŸ“… 1976 πŸ› Elsevier Science 🌐 French βš– 234 KB

m001d Ia UK for p9bli@8tlm 25 Ilo~~b~ 1975) The reaction of methylmagnesium bromide with aromatic ketones has been the subject of intense mechanistic studies in recent years.2 Since methylmagnesium bromide possesses no S-hydrogen atom, it is incapable of reducing ketones by S-hydrogen reduction and