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The formation of alkyl and alkenyl methanesulfonates and their reduction to hydrocarbons

✍ Scribed by W.J. Baumann; L.L. Jones; B.E. Barnum; H.K. Mangold

Publisher: Elsevier Science
Year: 1966
Tongue: English
Weight: 224 KB
Volume: 1
Category: Article
ISSN: 0009-3084
DOI: 10.1016/0009-3084(66)90008-9

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✦ Synopsis

Methanesulfonates of saturated and unsaturated long-chain alcohols are conveniently obtained in good purity and high yields. They can be converted, quantitatively, to hydrocarbons by reduction with lithium aluminum hydride. The procedure is applicable to the preparation of alkanes and alkenes, cis, trans-Isomerization of double bonds does not occur.

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