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The formation and thermal decomposition of 4-hydroperoxy-2-hydroxy-3,4,6-triisopropylcyclohexa-2,5-dienone

โœ Scribed by G. A. Abakumov; N. N. Vavilina; Yu. A. Kurskii; V. I. Nevodchikov; V. K. Cherkasov; A. S. Shavyr


Book ID
111555293
Publisher
Springer
Year
2003
Tongue
English
Weight
313 KB
Volume
52
Category
Article
ISSN
1573-9171

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The Reaction of 4-Hydroperoxy-2,4,6-trim
โœ Charles W. Jefford; Gรฉrald Bernardinelli; Ernest C. McGoran ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 311 KB

## Abstract The reaction of 4โ€hydroperoxyโ€2,4,6โ€trimethylcyclohexaโ€2,5โ€dienone with acetaldehyde using trimethylsilyl trifluoromethanesulfonate as catalyst gives 1,1โ€ฒโ€bis[(1,3,5โ€trimethylโ€4โ€oxoโ€2,5โ€cyclohexadienyl) peroxy]diethyl ether (**7**) in 70% yield. The structure of this unusual acetal was