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The first total synthesis of (−)-bitungolide E

✍ Scribed by J. Shashidhar; K. Mahender Reddy; Subhash Ghosh

Publisher: Elsevier Science
Year: 2011
Tongue: French
Weight: 385 KB
Volume: 52
Category: Article
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2011.04.008

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✦ Synopsis

The first total synthesis of (À)-bitungolide E is described. The key steps include a Myers' alkylation, modified Evans' syn aldol-reaction, using Crimmins protocol, Sharpless asymmetric epoxidation and ringclosing metathesis reaction.

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