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The First Total Syntheses of Ircinol A, Ircinal A, and Manzamines A and D

โœ Scribed by Winkler, Jeffrey D.; Axten, Jeffrey M.

Book ID
118745103
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
47 KB
Volume
120
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES

ChemInform Abstract: The First Total Syn
ChemInform Abstract: The First Total Syntheses of Ircinol A, Ircinal A, and Manzamines A and D.
โœ J. D. WINKLER; J. M. AXTEN ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 28 KB ๐Ÿ‘ 2 views

The First Total Syntheses of Ircinol A, Ircinal A, and Manzamines A and D. -Manzamine A (III) is synthesized in 17 steps from a readily available bicyclic precursor via ircinol A (Ia), ircinal A (Ib) and manzamine D (II) using the vinylogous amide photoaddition/fragmentation/Mannich closure sequence

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Enantioselective Total Syntheses of Ircinal A and Related Manzamine Alkaloids. -The enantioselective total synthesis of ircinal A (VIII) is presented involving a novel tandem Stille coupling-[4 + 2] cycloaddition reaction and two ring-closing metathesis reactions as the key steps. Thus, Stille coup