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ChemInform Abstract: The First Total Syntheses of Ircinol A, Ircinal A, and Manzamines A and D.

✍ Scribed by J. D. WINKLER; J. M. AXTEN

Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

The First Total Syntheses of Ircinol A, Ircinal A, and Manzamines A and D. -Manzamine A (III) is synthesized in 17 steps from a readily available bicyclic precursor via ircinol A (Ia), ircinal A (Ib) and manzamine D (II) using the vinylogous amide photoaddition/fragmentation/Mannich closure sequence. -(WINKLER,

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