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The first tetranuclear vanadium(V) peroxo complex: Preparation, vibrational spectra and X-ray crystal structure of K6[V4O4(O2)8(PO4)]·9H2O

✍ Scribed by Peter Schwendt; Alena Oravcová; Jarmila Tyršelová; František Pavelčík; Jaromír Marek

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
308 KB
Volume
15
Category
Article
ISSN
0277-5387

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✍ Michael Schindler; Werner Joswig; Werner H. Baur 📂 Article 📅 1997 🏛 Elsevier Science 🌐 English ⚖ 333 KB

4؉ , and As 5؉ , but none of them crystallize in space group Pn2n. In the K/V/P/N(C 2 H 5 ) 3 / H 2 O system, three different K phases were found: K 0.5 VOPO 4 • 1.5H 2 O, KVOPO 4 , and K-FVP-1 (Frankfurt vanadium phosphate, one, or for short, FVP-1). The microporous K-FVP-1 compound was synthesize