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The first synthesis of marine sesterterpene (+)-scalarolide

✍ Scribed by Xiang-Jian Meng; Yang Liu; Wen-Yuan Fan; Bin Hu; Wenting Du; Wei-Ping Deng

Book ID: 104096710
Publisher: Elsevier Science
Year: 2009
Tongue: French
Weight: 332 KB
Volume: 50
Category: Article
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2009.06.064

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✦ Synopsis

The synthesis of the first example of C12 oxygenated marine scalaranic sesterterpenes (+)-scalarolide was achieved through three key steps including the ring-opening rearrangement of epoxide, stereoselective Diels-Alder addition and one-pot c-butenolide formation process, and the absolute configuration of natural scalarolide was confirmed.

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