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The first synthesis of epoxy-mycolic acids

✍ Scribed by Dakhil Z. Al Kremawi; Juma’a R. Al Dulayymi; Mark S. Baird

Publisher
Elsevier Science
Year
2010
Tongue
French
Weight
590 KB
Volume
51
Category
Article
ISSN
0040-4039

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✦ Synopsis

We report the synthesis of single enantiomers of two epoxy-mycolic acids containing an a-methyl-transalkene.

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The synthesis of both enantiomers of lactobacillic acid and mycolic acid analogues
✍ Geoffrey D. Coxon; Stefan Knobl; Evan Roberts; Mark S. Baird; Juma R. Al Dulayym 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 219 KB

I1R, 12S)-Lactobacillic acid (1) has been prepared either from D-mannitol by asymmetric cyclopropanation or from cis-cy¢lopropane-l, 2-dimethanol by enzymatic dssymmetfisation. The syntheses of (IIS 12R)-lactobacillic acid ( 2) and (1R, 2S) l-(3'-methoxycmbonyipropyl)-2-octadecylcyciopropane (26) an