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The first synthesis of (±)-brevione B, an allelopathic agent isolated from Penicillium sp.

✍ Scribed by Hirosato Takikawa; Manabu Hirooka; Mitsuru Sasaki


Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
147 KB
Volume
44
Category
Article
ISSN
0040-4039

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✦ Synopsis


Breviones A E (1 5), allelopathic agents isolated from Penicillium brevicompactum Dierckx, are structurally unique pentacyclic or hexacyclic diterpenoid derivatives. The first synthesis of brevione B (2) was achieved by employing the double S N 2%-type tandem reaction as a key step.


📜 SIMILAR VOLUMES


(+)-Brevione A. The first member of a no
✍ Francisco A Macı́as; Rosa M Varela; Ana M Simonet; Horace G Cutler; Stephen J Cu 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 120 KB

+)-Brevione A, the first member of a novel family of bioactive spiroditerpenoids, a potential allelopathic agent, has been isolated from the ethyl acetate active fractions of the aqueous acetone extracts of semi-solid fermented Penicillium brevicompactum Dierckx. The structure displays the novel spi