The First Synthesis of (−)-Asperpentyn and Efficient Syntheses of (+)-Harveynone, (+)-Epiepoformin and (−)-Theobroxide
✍ Scribed by M. Teresa Barros; Christopher D. Maycock; M. Rita Ventura
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 132 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0947-6539
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✦ Synopsis
The First Synthesis of (À)-Asperpentyn and Efficient Syntheses of ()-Harveynone, ()-Epiepoformin and (À)-Theobroxide
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Efficient synthesis of 1-, 4-, and 5-caffeoylquinic acid was achieved in three or four steps with suitably protected quinic acid precursors, in overall yields of 41%, 36%, and 60% [from quinic acid (1)]. 1-Caffeoylquinic acid was prepared by esterification of acetone quinide 7 with caffeoyl chloride
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